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170

Plant and Process Technology

Equipment Design Methods

In the chemical industry bubble col-

umns are used as multiphase reactors.

In the literature numerous experimental

studies investigate the regimes of

homogeneous and heterogeneous

bubble flow with low gas velocities up

to 0.4 m/s and propose correlations

for the prediction of the gas content.

At the Institute of Plant and Process

Technology a bubble column with a

diameter of 300 mm and a total height

of 5.5 m was operated at high gas

velocities up to 1.2 m/s. Different mix-

tures of water and 72.7% invert sugar

solution were used to selectively vary

the properties of the liquid, especially

the viscosity. The photograph shows

heterogeneous bubble flow in the blue-

colored solution in the column. A com-

parison of the measurement data with

different correlations for homogeneous

bubble flows shows clear deviations,

whereas some correlations show sim-

ilar tendencies for the heterogeneous

bubble flow. Based on a semi-empirical

approach, the measured gas content

for the heterogeneous flow of bubbles

Heterogeneous flow

of bubbles in a

bubble column

Simulation of irrigated structured packing

Modeling and Thermodynamic Property Data

A dynamic model for open algae ponds was developed in

MATLAB at the Institute of Plant and Process Technology.

The model takes real weather data for selected locations

as input and enables the process engineer to optimize the

Typical dynamic behavior of pH value in open algae ponds

design of large raceway-type algae ponds. The developed

tool is essential since there is virtually no practical expe-

rience available on the behavior of these large ponds. A

possible CO

2

source is flue gas of power plants which can

either be used directly as feed for the algae pond or from

which the CO

2

can be captured and then used as a pure

CO

2

feed gas. Both options are covered in the MATLAB

model. Although growing algae in open ponds has been

done for decades, there is still a lot of research necessary

on how to efficiently grow algae in large systems with a

surface area per pond of 10 ha and greater and therefore

produce biofuels economically. At the Institute of Plant

and Process Technology a control scheme for CO

2

supply

has been developed with the fully dynamic MATLAB

model. It can be seen that for high yield algea a minimum

of three injection points are required for an algae pond

with a length of 1340 m and a width of 30 m. This ensures

that the pH-value stays within the range of 9.5 and 10.5.

The exemplary simulated location shown is Everglades,

Florida, taking a full year of available meteorological data.

can now be described for varying material properties with

a maximum deviation of ± 20%.

The model for dimensioning mass transfer columns based

on CAD data of packing elements, which was developed

at the institute, was successfully extended to structured

packings. The required coefficients were gained from

simulations with computational fluid dynamics. The picture

shows a representative element of structured packing

which is irrigated with liquid. The model can be used for a

more efficient design of distillation and absorption columns.